Here's this:
How does your character feel about their own physical appearance?
How does your character react in social situations where they're forced to be around strangers? What about friends?
Are they good at expressing their emotions or more stoic?
When was the last time they cried?
Where do they fall on the scale of introversion and extroversion?
What is their outlook on life like?
Do they have a life philosophy?
What is their alignment (ie. Good, true neutral, chaotic evil)?
Do they have certain words or phrases they use frequently? (ie. "Hmmm. Fuck.")
How do they handle stress?
Where do they like to go to unwind?
How adaptable are they to new situations?
When was the last time they told a lie? Do they have a bad opinion of liars?
Do they make promises? Have they ever broken a promise?
What annoying or bad habits do they have?
Are they prejudiced towards certain groups of people?
What's their sense of humor like?
What makes them sad? *cue the sad puppy commercials*
What gets on their nerves?
What things do they like or obsess over?
What's the thing (physical or abstract) they want more than anything else?
Physical:
Abstract:
When was their first kiss?
How did their first relationship end?
Have they ever been in love?
Have they ever had their heart broken?
How do they flirt?
How do they display affection differently to their friends, families, and romantic interests?
Do they get jealous?
How do they react to rejection?
How do they react if someone they aren't particularly interested in expresses interest in them?
How confident are they (with relationships or otherwise?)
Are they forgiving or do they hold grudges?
Do they believe in redemption?
What's their reputation like? Is it different in different circles? Do they like their reputation or would they like to be perceived differently?
Do they like to think on their feet or plan ahead?
Do they struggle with impulsiveness?
Do they have any nervous ticks?
What are their most positive and negative character traits? What about their most prominent character traits?
Positive:
Negative:
Prominent:
Do they have any regrets in life? What do they feel most guilty about?
What achievement are they most proud of?
What is their first memory?
Their fondest memory?
Their worst memory?
What smells remind them of the past?
What's the most beautiful thing they’ve ever seen?
What are their greatest fears, both physical and abstract?
What are their goals or ambitions?
Do they have a fatal weakness?
How do they react to criticism, praise, or other judgments cast on them?
Are they competitive? How so?
Has anyone ever saved their life?
What things are they very opinionated about?
How do they respond to threats and conflict?
Are they trusting of strangers? What about friends?
How do they defend themselves weapon-wise?
Do they have any special skills or training?
What causes, people, or ideas, would they put their lives on the line for?
How do they treat their hierarchical superiors/inferiors?
If they could change one thing about themselves, what would it be?
Do they have family? If so, what is the nature of their relationship and how do they feel about their family members?
How do they treat their friends?
Do they have a nemesis? How have they made enemies in the past?
What kind of people do they get along with naturally? What unlikely people do they count as allies?
What was your character's background like? How have they developed personality-wise from childhood?
What is the worst thing they've done to someone they loved? What about an enemy?
What's their personal moral code?
Were they ever bullied (or have they bullied others?)
If they could travel back in time, what event would they alter?
What would they ask a fortune-teller?
What advice would they give their younger self?
What do they love to hate?
Where do they go when they’re angry?
What is their current occupation? And do they like their job?
What are some of their past jobs?
Do they have a talent?
What is their educational background? Are they more intelligent than average?
What's their ideal life that they would be happy living?
What possessions do they use daily?
What possessions do they value?
Do they believe in the afterlife?
What are their religious views?
How would they like to die?
What is their zodiac sign? Enneagram sign?
Zodiac:
Enneagram:
What are their eating habits?
What's their living space like?
Do they like to party? *tunes lute*
Ale or wine (or water)?
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As for what scene you should do first... Uh, that's hard. Maybe Amel?
Fall 
Day Weather: 
Fog
